5,6-Diphenylpyridin-3-amine → 6-(3-Methoxyphenyl)-5-phenylpyridin-3-amine

HRID 41993Notes

Reaction equation

HRID 41993 reaction equation
C1(C2C=C(N)C=NC=2C2C=CC=CC=2)C=CC=CC=1.[CH3:20][O:21][C:22]1[CH:23]=[C:24]([C:28]2[C:33]([C:34]3[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=3)=[CH:32][C:31]([N+:40]([O-])=O)=[CH:30][N:29]=2)[CH:25]=[CH:26][CH:27]=1>>[CH3:20][O:21][C:22]1[CH:23]=[C:24]([C:28]2[N:29]=[CH:30][C:31]([NH2:40])=[CH:32][C:33]=2[C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)[CH:25]=[CH:26][CH:27]=1

Participants

3

Reactant 2

HCID 584158885,6-Diphenylpyridin-3-amineHCID 673943592-(3-Methoxyphenyl)-5-nitro-3-phenylpyridine

Product 1

HCID 584158776-(3-Methoxyphenyl)-5-phenylpyridin-3-amine

Procedure

Obtained (0.160 g, 69% of yield) following the procedure described in Intermediate 5 (step D) starting with 2-(3-methoxyphenyl)-5-nitro-3-phenylpyridine (0.84 mmol, 0.257 g).

Workup

  1. customObtained
  2. custom(0.160 g, 69% of yield)

Sources & evidence

ORD record
ord-1170a22087034aea9dab116e8639aa9c
Source dataset
uspto-grants-2013_09
Patent number
US08536165B2

Reaction notes

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