Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Methacrylic Acid | HCID 4093 | — |
| Reactant | Ethylene Oxide | HCID 6354 | — |
| Reactant | Styrene | HCID 7501 | — |
| Reactant | Butyl Acrylate | HCID 8846 | — |
| Reactant | Ammonium Persulfate | HCID 62648 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Solvent | Water | HCID 962 | — |
| Product | Methacrylic Acid | HCID 4093 | — |
| Product | Ethylene Oxide | HCID 6354 | — |
| Product | Styrene-methacrylic acid butyl acrylate sodium | HCID 86591398 | — |
Reaction Steps
First, 683 parts of water, 11 parts of sodium salt of sulfuric acid ester of ethylene oxide adduct of methacrylic acid (Eleminol RS-30 by Sanyo Chemical Industries, Ltd.), 83 parts of styrene, 83 parts of methacrylic acid, 110 parts of butyl acrylate, and 1 part of ammonium persulfate were put in a reaction vessel equipped with a stirrer and a thermometer, and stirred at 400 rpm for 15 minutes to obtain a white emulsion. The emulsion was heated to a temperature within the system of 75° C. and reacted for 5 hours. Next, 30 parts of 1% water solution of ammonium persulfate was added and matured at 75° C. for 5 hours to obtain an aqueous dispersion liquid of vinyl resin particles (a copolymer of styrene-methacrylic acid-butyl acrylate-sodium salt of sulfuric acid ester of ethylene oxide adduct of methacrylic acid). This was defined as [Fine Particle Dispersion Liquid 1].
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US08097393B2 |
|---|
| Source dataset | uspto-grants-2012_01 |
|---|
| ORD ID | ord-5afbe1a023154db5a0651082b816f2da |
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| Source note | uspto-grants-2012_01 |
|---|
