HRID42086

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：C=C1C[C@@H]2[C@H](CC[C@]3(C)C(=O)CC[C@@H]23)[C@@]2(C)CCC(=O)CC12

HCID67536381

未命名化合物

结构：C[C@]12CCCCC1[C@@H](CO)C[C@@H]1[C@@H]2CC[C@@]2(C)[C@H]1CC13OCCOC12OCCO3

HCID86635564

未命名化合物

PRODUCTS

生成物

结构：C[C@]12CCC(=O)CC1[C@@H](CO)C[C@@H]1[C@@H]2CC[C@]2(C)C(=O)CC[C@@H]12

HCID69010824

未命名化合物

收率 85%

PROCEDURE

实验过程

The title compound II-ad was prepared in 85% yield from 3,3:17,17-bis(ethylendioxy)-6α-hydroxymethylandrostane by the procedure described above for the preparation of 6-methyleneandrostane-3,17-dione (II-ac, Prepn. 13). The combined organic extracts were washed with H2O, dried and evaporated to dryness. 1H-NMR (300 MHz, acetone-d6, ppm from TMS): δ 3.50 (3H, m), 2.52-0.74 (21H, m), 1.11 (3H, s), 0.88 (3H, s).

WORKUP

后处理

washThe combined organic extracts were washed with H2O
customdried
customevaporated to dryness