HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 67536381, compound → 6alpha-Formamidoandrostane-3,17-dione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 67536381 | HCID 67536381 | — |
| Reactant | 17,17-Bis(ethylendioxy)-6alpha-formamidoandrostane | HCID 86635570 | — |
| Product | 6alpha-Formamidoandrostane-3,17-dione | HCID 86635569 | 96% |
Reaction Steps
The title compound II-aj was prepared in 96% yield from 3,3:17,17-bis(ethylendioxy)-6α-formamidoandrostane by the procedure described above for the preparation of 6-methyleneandrostane-3,17-dione (II-ac, Prepn. 13). The combined organic extracts were washed with H2O, dried over Na2SO4 and evaporated to dryness. 1H-NMR (300 MHz, DMSO-d6, ppm from TMS): δ 8.02-7.56 (2H, m), 3.74 (1H, m), 2.54-0.70 (20H, m), 1.04 (3H, s), 0.80 (3H, s).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08536160B2 |
| Source dataset | uspto-grants-2013_09 |
| ORD ID | ord-7503c659a08a46b7882976125f20a4a3 |
| Source note | uspto-grants-2013_09 |