HRID42116

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：C=C1C[C@@H]2[C@H](CC[C@]3(C)C(=O)CC[C@@H]23)[C@@]2(C)CCC(=O)CC12

HCID67536381

未命名化合物

结构：C=C1CC2CCCC[C@]2(C)[C@H]2CC[C@@]3(C)[C@@H](CC45OCCOC43OCCO5)[C@H]12

HCID86635586

未命名化合物

PRODUCTS

生成物

结构：C=C1CC2CC(=O)CC[C@]2(C)[C@H]2CC[C@]3(C)C(=O)CC[C@H]3[C@H]12

HCID67535109

未命名化合物

收率 87%

PROCEDURE

实验过程

The title compound II-aw was prepared in 87% yield from 3,3:17,17-bis(ethylendioxy)-7-methyleneandrostane by the procedure described above for the preparation of 6-methyleneandrostane-3,17-dione (I-ac, Prepn. 13). The combined organic extracts were washed with H2O, dried over Na2SO4 and evaporated to dryness. 1H-NMR (300 MHz, DMSO-d6, ppm from TMS): δ 4.70 (1H, m), 4.62 (1H, m), 2.20-1.10 (20H, m), 1.00 (3H, s), 0.88 (3H, s).

WORKUP

后处理

washThe combined organic extracts were washed with H2O
dry with materialdried over Na2SO4
customevaporated to dryness