HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Anhydride → HCID 13401939, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Anhydride | HCID 7918 | — |
| Reactant | Pyrylium, 2,4,6-triphenyl-, tetrafluoroborate(1-) | HCID 9930615 | — |
| Reactant | HCID 23710942 | HCID 23710942 | — |
| Product | HCID 13401939 | HCID 13401939 | — |
Reaction Steps
Sodium 4-biphenylacetate (25.0 g, 0.106 mol.) was placed in a suspension of 2,4,6-triphenylpyrylium tetrafluoroborate (41.0 g, 0.106 mol.) in 80 mL of acetic anhydride under nitrogen atmosphere and refluxed for 24 hours. The crude product was extracted with a 7:3 ratio mixture of hexane/dichloromethane. The solvent was stripped, and the crude product sublimed 4 times to achieve 99% purity. The practical yield following sublimations was 20%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08105700B2 |
| Source dataset | uspto-grants-2012_01 |
| ORD ID | ord-1dcf436f66534a10971573fec8993d93 |
| Source note | uspto-grants-2012_01 |