Cumen hydroperoxide → 2-Phenyl-2-propanol

HRID 426093Notes

Reaction equation

HRID 426093 reaction equation
[O-:1]O.[C:3]1([CH:9]([CH3:11])[CH3:10])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[H][H]>>[C:3]1([C:9]([OH:1])([CH3:11])[CH3:10])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Participants

3

Reactant 2

HCID 53627471Cumen hydroperoxideHCID 178418361HCID 178418361, compound

Product 1

HCID 120532-Phenyl-2-propanol

Procedure

Cumene hydroperoxide solution was pumped into the T-mixer with a flow of 0.250 ml/min. Hydrogen gas was fed into the T-mixer with a flow of 0.600 ml/min (1 bar). The T-mixer produced a taylor flow regime (liquid slugs). The product coming out of the reactor was collected. Samples were analysed with GC and HPLC. A conversion of 73% with >99% selectivity was obtained towards 2-phenyl-2-propanol.

Workup

  1. customThe T-mixer produced a taylor flow regime (liquid slugs)
  2. customwas collected

Sources & evidence

ORD record
ord-e0745c6b6d664c63be338f423798155f
Source dataset
uspto-grants-2012_01
Patent number
US08106242B2

Reaction notes

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