HuagongsheHuagongshe Chemistry Print Report · For research reference only
Furfuryl Alcohol → 5-[(Methylamino)methyl]-2-furanmethanol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Furfuryl Alcohol | HCID 7361 | — |
| Reactant | Sodium Carbonate | HCID 10340 | — |
| Reactant | Methylamine hydrochloride | HCID 6364545 | — |
| Solvent | Formaldehyde | HCID 712 | — |
| Product | 5-[(Methylamino)methyl]-2-furanmethanol | HCID 14671747 | — |
Reaction Steps
A mixture of 2-furanmethanol (49 g), methylamine hydrochloride (51.5 g) and 36% formaldehyde solution (50 ml) was stirred at 0°-3° for 3 hr and allowed to stand for 16 hr. Excess sodium carbonate was added and the slurry extracted with ethyl acetate. After removal of solvent the residue was distilled to give 5-(methylamino)methyl-2-furanmethanol (36.2 g) b.p. 111°-113° (0.2 mm).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04169855 |
| Source dataset | uspto-grants-1979_10 |
| ORD ID | ord-4e8ffe2da817488da1504a8af99f504c |
| Source note | uspto-grants-1979_10 |