HuagongsheHuagongshe Chemistry Print Report · For research reference only
Aluminium lithium hydride → 2-(3,4-Dimethoxyphenyl)ethyl 1-ethylcyclopropyl carbinol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Reactant | HCID 54360198 | HCID 54360198 | — |
| Product | 2-(3,4-Dimethoxyphenyl)ethyl 1-ethylcyclopropyl carbinol | HCID 23455766 | — |
Reaction Steps
2-(3,4-Dimethoxyphenyl)ethyl 1-ethylcyclopropyl carbinol [IV; Ar is 3,4-(CH3O)2C6H3, R is C2H5 ] was prepared from 15 g. of 2-(3,4-dimethoxyphenyl)vinyl 1-ethylcyclopropyl ketone (Preparation A4) and 2.2 g. of lithium aluminum hydride according to the procedure described above in Preparation B1, affording 10 g., b.p. 148°-150° C. (0.01 mm.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04171378 |
| Source dataset | uspto-grants-1979_10 |
| ORD ID | ord-e8b1ff10ea7747f5af96b5d401251cf8 |
| Source note | uspto-grants-1979_10 |