HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphorus tribromide → (6-Bromohex-3-en-1-yl)benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphorus tribromide | HCID 24614 | — |
| Reactant | Lithium Bromide | HCID 82050 | — |
| Reactant | HCID 10899201 | HCID 10899201 | — |
| Catalyst | Zinc bromide | HCID 10421208 | — |
| Product | (6-Bromohex-3-en-1-yl)benzene | HCID 53420932 | — |
Reaction Steps
6-Phenyl-3-hexenyl bromide [V; Ar is C6H5, R is H] was prepared from 16.5 g. of 2-phenylethyl cyclopropyl carbinol (Preparation B6), 21.5 g. of phosphorus tribromide, 17.65 g. of lithium bromide and 20.7 g. of zinc bromide according to the procedure given above in Preparation C1, affording 21 g. of product as a pale yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04171378 |
| Source dataset | uspto-grants-1979_10 |
| ORD ID | ord-6893066b42d845a39b101a0af1e6792a |
| Source note | uspto-grants-1979_10 |