1-[1,5-Di-(phenyl)-3-pentyl]-5-(2,3-dihydroxypropyl)-9,9-di-(2,3-dihydroxypropyl)-1,5,9-triazanonane → 1-[1,5-Di-(phenyl)-3-pentyl]-5-(2,3-dihydroxypropyl)-1,5,9-triazanonane

HRID 426908Notes

Reaction equation

HRID 426908 reaction equation
OC(CO)CN(CC(O)CO)CCCN.OC(CO)CN(CC(O)CO)CCCN(CC(O)CO)CCCN.[C:40]1([CH2:46][CH2:47][CH:48]([NH:57][CH2:58][CH2:59][CH2:60][N:61]([CH2:76][CH:77]([OH:80])[CH2:78][OH:79])[CH2:62][CH2:63][CH2:64][N:65](CC(O)CO)CC(O)CO)[CH2:49][CH2:50][C:51]2[CH:56]=[CH:55][CH:54]=[CH:53][CH:52]=2)[CH:45]=[CH:44][CH:43]=[CH:42][CH:41]=1>>[C:40]1([CH2:46][CH2:47][CH:48]([NH:57][CH2:58][CH2:59][CH2:60][N:61]([CH2:76][CH:77]([OH:80])[CH2:78][OH:79])[CH2:62][CH2:63][CH2:64][NH2:65])[CH2:49][CH2:50][C:51]2[CH:52]=[CH:53][CH:54]=[CH:55][CH:56]=2)[CH:41]=[CH:42][CH:43]=[CH:44][CH:45]=1

Participants

4

Reactant 3

HCID 234677961-[1,5-Di-(phenyl)-3-pentyl]-5-(2,3-dihydroxypropyl)-9,9-di-(2,3-dihydroxypropyl)-1,5,9-triazanonaneHCID 234677983,3'-[(3-Aminopropyl)azanediyl]di(propane-1,2-diol)HCID 234678171,1,5-Tri-(2,3-dihydroxypropyl)-1,5,9-triazanonane

Product 1

HCID 234678131-[1,5-Di-(phenyl)-3-pentyl]-5-(2,3-dihydroxypropyl)-1,5,9-triazanonane

Procedure

In a like manner and using analogous quantities, but employing N,N-di-(2,3-dihydroxypropyl)trimethylenediamine and 1,1,5-tri-(2,3-dihydroxypropyl)-1,5,9-triazanonane instead of 3,3'-(2,3-dihydroxypropylimino)bispropylamine there are prepared respectively N-[1,5-di-(phenyl)-3-pentyl]-N'-di-(2,3-dihydroxypropyl)trimethylenediamine, and 1-[1,5-di-(phenyl)-3-pentyl]-5-(2,3-dihydroxypropyl)-9,9-di-(2,3-dihydroxypropyl)-1,5,9-triazanonane.

Sources & evidence

ORD record
ord-32210d7d00884ef5837d882608833114
Source dataset
uspto-grants-1979_10
Patent number
US04172094

Reaction notes

Loading…