HuagongsheHuagongshe Chemistry Print Report · For research reference only
Mannitol → (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Mannitol | HCID 6251 | — |
| Reactant | HCID 178418489 | HCID 178418489 | — |
| Product | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | — |
Reaction Steps
A mixture of 7.46 g (41 mmole) of D-mannitol and 6.2 g (41 mmole) of xylitol is heated for 30 minutes to 80° C. with 67.5 g (227 mmole) of BEPDIB. After the readily volatile constituents have been distilled off in vacuo (10-3Torr), 11.6 g (96%) of bp. 108° C./10-3Torr and [α]D20 9.7 (c=6, CCl4) and 9.2 g (91%) of viscous residue are obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04172195 |
| Source dataset | uspto-grants-1979_10 |
| ORD ID | ord-11312da6a2834eb4a44313c189813ae9 |
| Source note | uspto-grants-1979_10 |