HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methylamine → N,3-Dimethylbut-3-en-1-amine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methylamine | HCID 6329 | — |
| Reactant | 2,6-Octadiene, 1-bromo-3,7-dimethyl-, (2E)- | HCID 5365867 | — |
| Reactant | HCID 86755596 | HCID 86755596 | — |
| Reactant | HCID 87871347 | HCID 87871347 | — |
| Solvent | Ethanol | HCID 702 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | N,3-Dimethylbut-3-en-1-amine | HCID 13212923 | — |
| Product | 280755-56-8 | HCID 22251448 | — |
| Product | HCID 86755593 | HCID 86755593 | — |
| Product | HCID 86755594 | HCID 86755594 | — |
Reaction Steps
N-methylgeranylamine used in the examples was prepared by treatment of geranyl bromide with 12 fold excess of methylamine in ethanol. The product was isolated by extraction into ethyl ether and distillation. N-methylfarnesylamine, N-methylcitronellylamine and N-methyl-3-methyl-3-butenylamine are prepared in a similar manner. N-methyloleylamine was prepared by methylation of the N-oleylacetamide potassium salt followed by hydrolysis.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06313348B1 |
| Source dataset | uspto-grants-2001_11 |
| ORD ID | ord-522a3076d6c14b92ada5f3b959a89a75 |
| Source note | uspto-grants-2001_11 |