HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 429520Generated: October 29, 2026
Chloroform → (Trichloromethylthio)methylbenzene
https://huagongshe.com/reaction/429520
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Chloroform | HCID 6212 | — |
| Reactant | Benzyl Thiocyanate | HCID 18170 | — |
| Catalyst | Benzyl triethylammonium chloride | HCID 66133 | — |
| Solvent | Sodium Hydroxide | HCID 14798 | — |
| Product | (Trichloromethylthio)methylbenzene | HCID 23504086 | — |
Reaction Steps
Benzyl thiocyanate (29.8 g, 0.2 mol), chloroform (76 g, 0.6 mol) and triethylbenzylammonium chloride (0.5 g, 0.002 mol) were stirred vigorously. 40 ml of 50% aqueous sodium hydroxide were added clowly to this solution (mildly exothermic). The temperature increased to 40° C. and was maintained thereat for 4 h with efficient stirring.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US06316636B1 |
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| Source dataset | uspto-grants-2001_11 |
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| ORD ID | ord-e29281b96517427c80e16fded103244c |
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| Source note | uspto-grants-2001_11 |
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