関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Styrene | HCID 7501 | — |
| 反応物 | Chlorobenzene | HCID 7964 | — |
| 生成物 | 1,1-Diphenylethylene | HCID 10740 | 12.4% |
| 生成物 | trans-Stilbene | HCID 638088 | 86.7% |
| 生成物 | cis-Stilbene | HCID 5356785 | 0.9% |
反応手順
A reaction is performed as described in Example 1, except that 102.8 mg (0.99 mmol) of styrene and 164.8 mg (1.46 mmol) of chlorobenzene are used, and the reaction mixture is stirred at 150° C. for 5.5 hours. With 94.6% conversion of Cl-benzene, an 82.1% yield of Heck products (86.7% trans-stilbene, 0.9% cis-stilbene, 12.4% 1,1-diphenylethene) is obtained.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06316675B1 |
|---|
| 出典データセット | uspto-grants-2001_11 |
|---|
| ORD ID | ord-0f3dd49aeb5e4d00b6d810eb17ec34cb |
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| 出典メモ | uspto-grants-2001_11 |
|---|
