HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cyclohexanone → N,N-Dipropylcyclohexanamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cyclohexanone | HCID 7967 | — |
| Reactant | Dipropylamine | HCID 8902 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | N,N-Dipropylcyclohexanamine | HCID 524233 | — |
Reaction Steps
Cyclohexanone (0.415 cm3, 4.0 mmol), di-n-propylamine (0.548 cm3, 4.0 mmol) and [Ir(COD)(dppb)][PF6] (0.070 g, 2 mol %) were reacted in dichloromethane at 20° C. for 24 hrs, at approx. 1 bar H2. The yield of N,N-di-n-propylcyclohexylamine obtained was 43.5%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06323370B1 |
| Source dataset | uspto-grants-2001_11 |
| ORD ID | ord-b1497627dc0543f89d0b766648a5fdec |
| Source note | uspto-grants-2001_11 |