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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 430909Generated: October 25, 2026

Styrene → p-Tert-butoxystyrene styrene

https://huagongshe.com/reaction/430909

Reaction equation

Participants

RoleNameHCIDCharge
ReactantStyreneHCID 7501—
Reactant1-(Tert-butoxy)-4-ethenylbenzeneHCID 577531—
Productp-Tert-butoxystyrene styreneHCID 69102216—

Reaction Steps

With the use of 81.1 g (0.46 mole) of p-tert-butoxystyrene and 4.6 g (0.04 mole) of styrene, the same polymerization reaction and after-treatment as Production example 2-(1) were conducted to give 77.1 g of poly(p-tert-butoxystyrene/styrene) as white powders. A ratio of p-tert-butoxystyrene unit and styrene unit in the obtained polymer was about 92:8 by 1HNMR. Mw: about 20000, molecular dispersion: 1.90 (GPC method; polystyrene as standard).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06656660B1
Source datasetuspto-grants-2003_12
ORD IDord-b886aeadfd1d4c3f8ef665a00c2f0cf7
Source noteuspto-grants-2003_12