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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 431151Generated: November 3, 2026

Benzyl mercaptan → HCID 86588940, compound

https://huagongshe.com/reaction/431151

Reaction equation

Participants

RoleNameHCIDCharge
ReactantBenzyl mercaptanHCID 7509—
Reactant1-Ethynyl-4-fluorobenzeneHCID 522627—
ReactantSodiumHCID 5360545—
ProductHCID 86588940HCID 86588940—

Reaction Steps

A solution of 4-fluorophenylacetylene (0.02 mol) and benzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-fluorostyryl benzylsulfide. The title compound was obtained in 76% yield following oxidation. 1HNMR (CDC13) δ4.54 (2H, s), 6.68 (1H, d, JH,H=11.94), 7.12-7.58 (9H aromatic+1H ethylenic).

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS06656973B2
Source datasetuspto-grants-2003_12
ORD IDord-74fc582e6b2c4ae6991e80ba8533c6d5
Source noteuspto-grants-2003_12