HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 20607511, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 1,3-Benzenedicarboxylic acid, 5-hydroxy-, 1,3-dimethyl ester | HCID 83065 | — |
| Reactant | 1-Naphthaleneboronic acid | HCID 254532 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 20607511 | HCID 20607511 | 76% |
Reaction Steps
A solution of 5-hydroxyisophthalic acid dimethylester (208 mg, 1 mmol) and 2 naphthaleneboronic acid (172 mg, 1 mmol), Cu (OAc)2 (61 mg, 0.5 mmol), Et3N (0.16 ml, 1.2 mmol) in 10 ml methylenechloride was refluxed for overnight. The reaction mixture was purified by silica gel column eluted by 15% Teac in hexane to afford the product (76% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06656971B2 |
| Source dataset | uspto-grants-2003_12 |
| ORD ID | ord-f4fb8d6b33d041dda60d829db8128afa |
| Source note | uspto-grants-2003_12 |