HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → HCID 23445194, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Benzenamine, 3-(methylthio)- | HCID 15693 | — |
| Reactant | Ethyl orthoformate | HCID 31214 | — |
| Reactant | Ethyl nitroacetate | HCID 69379 | — |
| Catalyst | Iron | HCID 23925 | — |
| Product | HCID 23445194 | HCID 23445194 | — |
Reaction Steps
Following the general method described in example 234, 3-(methylthio)aniline was reacted with triethyl orthoformate, ethyl nitroacetate and acetic acid followed by treatment with triethyl orthoformate, iron and acetic acid and subsequent alkaline hydrolysis. The title compound was obtained as a grey crystalline solid. Mp. 190-192° C. (H2O/dioxane), MS: m/e=234 (M+).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06667335B2 |
| Source dataset | uspto-grants-2003_12 |
| ORD ID | ord-e0e89c22dafd435b9479628bf8426f6b |
| Source note | uspto-grants-2003_12 |