HRID433654

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID61221

Dibutylstannane oxide

C8H18OSn

反应SMILES：CC(C)(C)c1cc(CCC(=O)O)cc(-n2nc3ccc(Cl)cc3n2)c1O

HCID18008718

未命名化合物

PRODUCTS

产物

反应SMILES：CC(C)(C)c1cc(CCC(=O)[O-])cc(-n2nc3ccc(Cl)cc3n2)c1O.CC(C)(C)c1cc(CCC(=O)[O-])cc(-n2nc3ccc(Cl)cc3n2)c1O.CCC[CH2][Sn+2][CH2]CCC

HCID22715280

未命名化合物

PROCEDURE

实验过程

Following the synthetic procedure of Example 25, the title compound is prepared by reaction of the corresponding equivalent amounts of 3-(5-chloro-2H-benzotriazol-2-yl)-5-tert-butyl-4-hydroxyhydrocinnamic acid and dibutyltin oxide to give the title compound as a yellow resin (47.24 g, 97.6% yield) whose structure is consistent with 1Hnmr.

来源与证据

来源类型: Open Reaction Database
ORD记录: ord-780c54e2a7c84ce48d07b909bfd01425
来源数据集: uspto-grants-2003_12
DOI: 10.6084/m9.figshare.5104873.v1
专利号: US06667403B2
来源说明: uspto-grants-2003_12

反应SMILES

[Cl:1][C:2]1[CH:26]=[CH:25][C:5]2=[N:6][N:7]([C:9]3[CH:10]=[C:11]([CH:17]=[C:18]([C:21]([CH3:24])([CH3:23])[CH3:22])[C:19]=3[OH:20])[CH2:12][CH2:13][C:14]([OH:16])=[O:15])[N:8]=[C:4]2[CH:3]=1.[CH2:27]([Sn:31](=O)[CH2:32][CH2:33][CH2:34][CH3:35])[CH2:28][CH2:29][CH3:30]>>[Cl:1][C:2]1[CH:26]=[CH:25][C:5]2=[N:6][N:7]([C:9]3[CH:10]=[C:11]([CH:17]=[C:18]([C:21]([CH3:22])([CH3:23])[CH3:24])[C:19]=3[OH:20])[CH2:12][CH2:13][C:14]([O-:16])=[O:15])[N:8]=[C:4]2[CH:3]=1.[Cl:1][C:2]1[CH:26]=[CH:25][C:5]2=[N:6][N:7]([C:9]3[CH:10]=[C:11]([CH:17]=[C:18]([C:21]([CH3:22])([CH3:23])[CH3:24])[C:19]=3[OH:20])[CH2:12][CH2:13][C:14]([O-:16])=[O:15])[N:8]=[C:4]2[CH:3]=1.[CH2:27]([Sn+2:31][CH2:32][CH2:33][CH2:34][CH3:35])[CH2:28][CH2:29][CH3:30]