1-Butanol, 4-bromo-, 1-acetate → HCID 54696727, compound

HRID 434094Notes

Reaction equation

HRID 434094 reaction equation
[CH2:1]([O:5][C:6]1[C:7](=[O:18])[O:8][C:9]2[CH:16]=[CH:15][C:14]([OH:17])=[CH:13][C:10]=2[C:11]=1[OH:12])[CH2:2][CH2:3][CH3:4].[C:19]([O:22][CH2:23][CH2:24][CH2:25][CH2:26]Br)(=[O:21])[CH3:20]>>[CH2:1]([O:5][C:6]1[C:7](=[O:18])[O:8][C:9]2[CH:16]=[CH:15][C:14]([O:17][CH2:26][CH2:25][CH2:24][CH2:23][O:22][C:19](=[O:21])[CH3:20])=[CH:13][C:10]=2[C:11]=1[OH:12])[CH2:2][CH2:3][CH3:4]

Participants

3

Reactant 2

HCID 784911-Butanol, 4-bromo-, 1-acetateHCID 54696992HCID 54696992, compound

Product 1

HCID 54696727HCID 54696727, compound

Procedure

In the same manner as in Reference Example 1, except that an equimolar amount of 3-butoxy-4,6-dihydroxy-2H-1-benzopyran-2-one was used in place of 3-ethoxy-4,5-dihydroxy-2H-1-benzopyran-2-one, and 4-bromobutyl acetate was used in place of 2-bromoethyl acetate in Reference Example 1, 3-butoxy-4-hydroxy-6-(4-acetoxybutoxy)-2H-1-benzopyran-2-one was obtained.

Sources & evidence

ORD record
ord-a33e25f7a2ed438782c7b8154af76c85
Source dataset
uspto-grants-2003_12
Patent number
US06670391B2

Reaction notes

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