Dichloromethane → HCID 86587455, compound

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Reaction Steps

Inside a nitrogen purged drybox, the palladium catalyst, {[(2,6-iPr2Ph)2DABMe2]Pd(CH2CH2CH2CO2Me)}BAF (77 mg, 0.053 mmol) was dissolved in CH2Cl2 (2 ml) and cyclopentene (2 ml) and 3-MeCyp (1 ml) added. The solution was stirred for 4 days after which the volatiles were removed. MeOH was added and the polymer filtered, washed well with MeOH and finally with 2% Irganox® 1010/acetone solution and dried. Yield=1.06 g. Tm (DSC)=210.5° C., Tg (DSC)=73° C. 13C-NMR (TCB, 120° C.) indicated ˜5% 3-MeCyp incorporation.

Provenance & Evidence