HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Nitrobenzyl chloride → HCID 13178725, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Nitrobenzyl chloride | HCID 11921 | — |
| Reactant | Thiourea | HCID 2723790 | — |
| Solvent | Butyl Chloride | HCID 8005 | — |
| Product | HCID 13178725 | HCID 13178725 | 77% |
Reaction Steps
A solution of 34.3 g of o-nitrobenzyl chloride and 15.2 g of thiourea in 250 ml of #2B alcohol was refluxed for 11/2 hours. The solution was cooled to 60° and 250 ml of 1-chlorobutane added. Further cooling to 20° yielded a precipitate which was filtered, washed with 1-chlorobutane and dried at 65° to give 38.1 g of 2-nitrophenylmethyl carbamimidothioate hydrochloride, m.p. 190°-192°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04397679 |
| Source dataset | uspto-grants-1983_08 |
| ORD ID | ord-fabdfe8ceaba46e9ac76050c30f2c125 |
| Source note | uspto-grants-1983_08 |