Sodium Sulfate → Sodium Sulfate

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The conventional method of precipitating calcium tungstate from an aqueous solution of sodium tungstate which also contains sodium sulfate is adding calcium chloride. The presence of sodium sulfate in the solution inevitably results in co-precipitation of calcium sulfate, thereby contaminating the calcium tungstate precipitate. The precipitate is therefore typically calcined with carbon at about 950° C. to reduce the calcium sulfate to calcium oxide plus a sulfur dioxide offgas. This process is unsatisfactory because it consumes large quantities of calcium chloride, and because it generates large volumes sodium chloride solution and sulfur dioxide offgas which must be disposed of. In addition, the calcium oxide byproduct dilutes the calcium tungstate product and lowers the WO3 content thereof.

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