5,10-Dihydro-5,10-dimethylphenazine → Tetrafluoroborate

HRID 434542Notes

Reaction equation

HRID 434542 reaction equation
[F:1][B-:2]([F:5])([F:4])[F:3].[CH3:6][N:7]1[C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[N:14]([CH3:21])[C:13]2[CH:12]=[CH:11][CH:10]=[CH:9][C:8]1=2.CN1C2C(=CC=CC=2)N(C)C2C=CC=CC1=2>CC#N>[F:1][B-:2]([F:5])([F:4])[F:3].[CH3:21][N:14]1[C:13]2[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=2)[N:7]([CH3:6])[C:20]2[CH:19]=[CH:18][CH:17]=[CH:16][C:15]1=2

Participants

5

Reactant 2

HCID 2886795,10-Dihydro-5,10-dimethylphenazineHCID 86738967HCID 86738967, compound

Product 2

HCID 26255TetrafluoroborateHCID 2886795,10-Dihydro-5,10-dimethylphenazine

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent2×

Procedure

At first, perfluoroborate of cation-radical of N,N'-dimethyl phenazine (tetrafluoroborate) ##STR14## was prepared. Said substance was prepared according to the procedure similar to that specified in Example 3. For this purpose, 0,001 mole of N,N'-dimethyl phenazine was dissolved in 150 cm3 of CH3CN. The resulting solution was blown through with argon, and 0.001 mole of NOBF4 dissolved in 50 cm3 of CH3CN was added thereto. Further treatment and separation of the end product were carried out as specified in Example 3. Dark green crystals of tetrafluoroborate of cation-radical of N,N'-dimethyl phenazine were obtained. The yield was 91%.

Workup

  1. customwas prepared
  2. additionwas added
  3. customFurther treatment and separation of the end product

Sources & evidence

ORD record
ord-9db1f6115e9e4ab6932feeb4201a0c2f
Source dataset
uspto-grants-1983_08
Patent number
US04397922

Reaction notes

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