1,3-Butadiene → HCID 54171689, compound

HRID 434792Notes

Reaction equation

HRID 434792 reaction equation
[CH2:1]([OH:9])[CH:2]=[CH:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH2:8].[CH2:10]=[CH:11][CH:12]=[CH2:13]>>[CH2:8]=[C:7]([CH2:10][CH:11]=[CH:12][CH3:13])[CH2:6][CH2:5][CH2:4][CH:3]=[CH:2][CH2:1][OH:9]

Participants

3

Reactant 2

HCID 78451,3-ButadieneHCID 320122,7-Octadien-1-ol

Product 1

HCID 54171689HCID 54171689, compound

Procedure

Additional examples of reactions according to the invention are of 2,7-octadiene-1-ol with 1,3-butadiene to yield 7-methylene-2,9-undecadiene-1-ol and the reaction of 1-methoxy-2,7-octadiene with 1,3-butadiene to yield 1-methoxy-7-methylene-2,9-undecadiene. Additional examples of suitable compounds of Formula (II) are 1-acetoxy-2,6-dimethyl-2,7-octadiene, 1-methoxy-2,6-dimethyl-2,7-octadiene, 2-acetoxy-3,8-decadiene, 2-methoxy-3,8-decadiene and 3,8-decadiene-2-ol. Additional examples of suitable compounds of Formula (III) are isoprene and piperylene.

Sources & evidence

ORD record
ord-542f6ae36719493fbb37d71753af453a
Source dataset
uspto-grants-1983_08
Patent number
US04399301

Reaction notes

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