HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylthiocarbamoyl chloride → HCID 178447889, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylthiocarbamoyl chloride | HCID 27871 | — |
| Reactant | 1-(Bromomethyl)-4-ethoxybenzene | HCID 14775668 | — |
| Reactant | HCID 178447900 | HCID 178447900 | — |
| Reactant | HCID 178447920 | HCID 178447920 | — |
| Product | HCID 178447889 | HCID 178447889 | — |
Reaction Steps
31.5 g of 4-(trans-4-n-propylcyclohexyl)-2-bromothiophenol [prepared from 4-(trans-4-n-propylcyclohexyl)-2-bromophenol obtained according to Example 3 by reaction with dimethylthiocarbamoyl chloride, thermal rearrangement and hydrolysis analogously to Organic Syntheses, Volume 51 (1971), pages 139-142] is etherified with 21.5 g of 4-ethoxybenzyl bromide analogously to Example 1(d). There is obtained 40.2 g of 4-(trans-4-n-propylcyclohexyl)-2-bromophenyl-(4-ethoxybenzyl)thioether.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04400293 |
| Source dataset | uspto-grants-1983_08 |
| ORD ID | ord-9f05703a65b54b159173f8d5fa1535b0 |
| Source note | uspto-grants-1983_08 |