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HRID435239

反应详情

EQUATION

反应方程式

HRID 435239 的结构方程式

REACTANTS

反应物

2
结构：O=S(=O)(Cl)Cl
HCID24648

Sulfuryl chloride

Cl2O2S

结构：CCOC(=O)C(=NOC(C)C)C(C)=O
HCID539498

Butanoic acid, 2-[(1-methylethoxy)imino]-3-oxo-, ethyl ester, (Z)-

C9H15NO4

PRODUCTS

生成物

1
结构：CCOC(=O)C(=NOC(C)C)C(=O)CCl
HCID54571966

未命名化合物

收率 100.1%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(=O)O
溶剂HCID176

Acetic Acid

C2H4O2

PROCEDURE

实验过程

Ethyl 2-iso-propoxyimino-3-oxobutyrate (syn isomer 35.4 g.), sulfuryl chloride (24.5 g.) and acetic acid (35.4 ml.) were treated in a similar manner to that of Example D-(2) to give ethyl 4-chloro-3-oxo-2-iso-propoxyiminobutyrate (syn isomer, 41.5 g.), oil.