HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Carbonate → 2-Ethyl-3,6,6-trimethyl-1-crotonoyl-2-cyclohexene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 1-(2-Ethyl-3,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-1-one | HCID 21439668 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 2-Ethyl-3,6,6-trimethyl-1-crotonoyl-2-cyclohexene | HCID 21439669 | 91.5% |
Reaction Steps
A suspension of 3.5 g (15.9 mmol) of 2-ethyl-3,6,6-trimethyl-1-[but-3-enoyl]-2-cyclohexene and 2.0 g of potassium carbonate in 40 ml of acetone is stirred at room temperature under nitrogen for 24 hours. The salt is removed by filtration and the filtrate concentrated. After fractional distillation, the residue yields 3.2 g (91.5%) of 2-ethyl-3,6,6-trimethyl-1-crotonoyl-2-cyclohexene; boiling point 59°-60° C/0.04 mm Hg; nD20 = 1.4952.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04006108 |
| Source dataset | uspto-grants-1977_02 |
| ORD ID | ord-ee159bd06b994efb9828ec727f511a39 |
| Source note | uspto-grants-1977_02 |