HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thionyl Chloride → 3-Bromo-6-(phenylthio)-benzyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thionyl Chloride | HCID 24386 | — |
| Reactant | 3-Bromo-6-(phenylthio)-benzyl alcohol | HCID 54261623 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 3-Bromo-6-(phenylthio)-benzyl chloride | HCID 21456037 | — |
Reaction Steps
445 g of 3-bromo-6-(phenylthio)-benzyl alcohol are dissolved in 800 ml of benzene and heated under reflux. 165 ml of thionyl chloride are added dropwise thereto and the mixture is boiled for a further 90 minutes. After evaporation of the solvent, there is obtained 3-bromo-6-(phenylthio)-benzyl chloride as a brown oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04006144 |
| Source dataset | uspto-grants-1977_02 |
| ORD ID | ord-f4650300d9c445579bf5b86af562d472 |
| Source note | uspto-grants-1977_02 |