Potassium Hydroxide → HCID 178442626, compound

HRID 435791Notes

Reaction equation

HRID 435791 reaction equation
[C:1]([C:6]([C:20]([O:22]CC)=[O:21])([CH2:18][CH3:19])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]1[C:13](=[O:17])[CH2:14][CH2:15][CH:16]=1)([O:3]CC)=[O:2].[CH:25]1[C:26](/[CH:41]=[N:42]/[OH:43])=[CH:27][CH:28]=[N+:29]([CH2:31][N+:32]2[CH:37]=[CH:36][C:35](/[CH:38]=[N:39]/[OH:40])=[CH:34][CH:33]=2)[CH:30]=1.[Br-:44].[Br-].[OH-].[K+]>CO>[C:1]([C:6]([C:20]([OH:22])=[O:21])([CH2:18][CH3:19])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]1[C:13](=[O:17])[CH2:14][CH2:15][CH:16]=1)([OH:3])=[O:2].[CH:27]1[C:26](/[CH:41]=[N:42]/[OH:43])=[CH:25][CH:30]=[N+:29]([CH2:31][N+:32]2[CH:33]=[CH:34][C:35](/[CH:38]=[N:39]/[OH:40])=[CH:36][CH:37]=2)[CH:28]=1.[Br-:44].[Br-:44]

Participants

4

Reactant 2

HCID 14797Potassium HydroxideHCID 178471350HCID 178471350, compound

Product 1

HCID 178442626HCID 178442626, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Treatment of 2-(6,6-dicarbethoxyoctyl)-2-cyclopentenone methoxime (Example 27) with potassium hydroxide, and 1:1 aqueous methanol in the manner described in Example 20 gives a light yellow oil.

Workup

  1. customgives a light yellow oil

Sources & evidence

ORD record
ord-f05be79a47c2482f8bd03d7df27e3398
Source dataset
uspto-grants-1977_02
Patent number
US04006179

Reaction notes

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