Sodium Methoxide → HCID 54711094, compound

HRID 435830Notes

Reaction equation

HRID 435830 reaction equation
[CH2:1]([N:3]([C:7]1[CH2:12][CH:11]([CH3:13])[CH2:10][CH2:9][C:8]=1[C:14]([O-:16])=O)[C:4](=[O:6])[CH3:5])[CH3:2].C[O-].[Na+]>O1CCOCC1>[CH2:1]([N:3]1[C:7]2[CH2:12][CH:11]([CH3:13])[CH2:10][CH2:9][C:8]=2[C:14]([OH:16])=[CH:5][C:4]1=[O:6])[CH3:2]

Participants

4

Reactant 2

HCID 10942334Sodium MethoxideHCID 21428341HCID 21428341, compound

Product 1

HCID 54711094HCID 54711094, compound

Reagents, catalysts & solvents 1

HCID 312751,4-DioxaneSolvent

Procedure

The reaction of a 1:9 mixture of the methyl and ethyl esters of 2-(N-ethyl-acetamido)-4-methyl-cyclohex-1-ene-1-carboxylate (36.3 g; 0.144 mole) with dry sodium methoxide in dioxan as described in Example 8 gave the title product as a white crystalline solid; m.p. (EtOH) 335° - 338° C

Sources & evidence

ORD record
ord-597318fbcd4c4decba1dc61c16b53ee6
Source dataset
uspto-grants-1977_02
Patent number
US04006237

Reaction notes

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