HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sulfuric Acid → 4-oxo-7-(3-[2-propylphenoxy]propoxy)-4H-1-benzopyran-2-carboxylic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sulfuric Acid | HCID 1118 | — |
| Reactant | 1,4-Dioxane | HCID 31275 | — |
| Reactant | 4-Oxo-7-(3-[2-propylphenoxy]propoxy)-4H-1-benzopyran-2-carbonitrile | HCID 13091003 | — |
| Product | 4-oxo-7-(3-[2-propylphenoxy]propoxy)-4H-1-benzopyran-2-carboxylic acid | HCID 13090987 | — |
Reaction Steps
A suspension of 1.0 parts of 4-Oxo-7-(3-[2-propylphenoxy]propoxy)-4H-1-benzopyran-2-carbonitrile in 50 parts of dioxane and 50 parts of 38% v /v sulphuric acid was heated on a steam can for eighteen hours. The solid obtained on cooling was collected, washed with water and crystallised from acetone to give 0.09 parts of 4-oxo-7-(3-[2-propylphenoxy]propoxy)-4H-1-benzopyran-2-carboxylic acid, m.pt. 161°-163°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04006245 |
| Source dataset | uspto-grants-1977_02 |
| ORD ID | ord-151537e1f9f8475486bd811836add9aa |
| Source note | uspto-grants-1977_02 |