HRID436060

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID14797

Potassium hydroxide

HKO

结构：CCOC(=O)C(CC)(CCCCCC1=CCCC1=O)C(=O)OCC.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]

HCID178471350

未命名化合物

PRODUCTS

生成物

结构：CCC(CCCCCC1=CCCC1=O)(C(=O)O)C(=O)O.O/N=C/c1cc[n+](C[n+]2ccc(/C=N/O)cc2)cc1.[Br-].[Br-]

HCID178442626

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

Treatment of 2-(6,6-dicarbethoxyoctyl)-2-cyclopentenone methoxime (Example 26) with potassium hydroxide, and 1:1 aqueous methanol in the manner described in Example 20 gives light yellow oil.

WORKUP

后处理

customgives light yellow oil

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e86b6da9ca134261a93e0b59f242a3d1
来源数据集: uspto-grants-1977_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04007210
来源说明: uspto-grants-1977_02

反应 SMILES

[C:1]([C:6]([C:20]([O:22]CC)=[O:21])([CH2:18][CH3:19])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]1[C:13](=[O:17])[CH2:14][CH2:15][CH:16]=1)([O:3]CC)=[O:2].[CH:25]1[C:26](/[CH:41]=[N:42]/[OH:43])=[CH:27][CH:28]=[N+:29]([CH2:31][N+:32]2[CH:37]=[CH:36][C:35](/[CH:38]=[N:39]/[OH:40])=[CH:34][CH:33]=2)[CH:30]=1.[Br-:44].[Br-].[OH-].[K+]>CO>[C:1]([C:6]([C:20]([OH:22])=[O:21])([CH2:18][CH3:19])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][C:12]1[C:13](=[O:17])[CH2:14][CH2:15][CH:16]=1)([OH:3])=[O:2].[CH:27]1[C:26](/[CH:41]=[N:42]/[OH:43])=[CH:25][CH:30]=[N+:29]([CH2:31][N+:32]2[CH:33]=[CH:34][C:35](/[CH:38]=[N:39]/[OH:40])=[CH:36][CH:37]=2)[CH:28]=1.[Br-:44].[Br-:44]