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HRID436246

反应详情

EQUATION

反应方程式

HRID 436246 的结构方程式

REACTANTS

反应物

3
结构：[O]=[Cr](=[O])([OH])[OH]
HCID24425

Chromic(VI) acid

H2CrO4

结构：CC(=O)OC1C=CC(=O)C1
HCID343117

4-Oxocyclopent-2-en-1-yl acetate

C7H8O3

结构：CC(=O)O[C@@H]1C=C[C@@H](O)C1
HCID12773776

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)O[C@@H]1C=C[C@H](O)C1
HCID9855498

(1R,4S)-cis-4-Acetoxy-2-cyclopenten-1-ol

C7H10O3

PROCEDURE

实验过程

The trans-3-acetoxy-5-hydroxycyclopent-1-ene obtained by using baker's yeast and whose absolute configuration was determined to be of R-configuration was converted to 4-acetoxycyclopent-2-en-1-one by oxidation with chromic acid. When the specific rotation of this compound was found to be +74°.

WORKUP

后处理

  1. customto be +74°