Carbon Disulfide → HCID 21454004, compound

Participants

Reaction Steps

A mixture of 412.0 g. (4.0 moles) triethylamine, 60.8 g. (0.8 mole) carbon disulfide, 73.2 g. (0.4 mole) anhydrous zinc acetate and 163.6 g. (0.8 mole) 5-methyl-2-trichloromethyloxazolidine was stirred at 40° C. for 1 hour. After standing overnight at room temperature, the reaction mixture was diluted with water and filtered to give 417.8 g. of the desired crude product sintering at 89° C. and melting with decomposition at 128°-150° C. Extraction with chloroform and repeated crystallization from benzene gave an analytical sample melting at 170°-176° C. with decomposition. It had the following analysis: Found: N, 4.30; Zn, 10.16. Calc. for C12H14Cl6N2O2S4Zn: N, 4.48; Zn, 10.47.

Provenance & Evidence