HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Disulfide → Triethylammonium 2-Trichloromethyl-3-oxazolidinecarbodithioate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Disulfide | HCID 6348 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 2-(Trichloromethyl)oxazolidine | HCID 99029 | — |
| Product | Triethylammonium 2-Trichloromethyl-3-oxazolidinecarbodithioate | HCID 22766662 | — |
Reaction Steps
A mixture of 114 g (0.60 mole) 2-trichloromethyloxazolidine, 121.2g. (1.2 moles) triethylamine and 68.4 g. (0.9 mole) carbon disulfide was heated at 50° for 7 hours and then was left standing for 18 hours at room temperature. The yellow solids were filtered, stirred with anhydrous ethyl ether, and filtered again to obtain 195.5 g (88.7% conversion) of the desired product, m.p. 107°-110° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04008244 |
| Source dataset | uspto-grants-1977_02 |
| ORD ID | ord-03c5ee330ff449fcb8297588d418eeb9 |
| Source note | uspto-grants-1977_02 |