Cyclopropanemethanol → Cyclopropylmethyl 3,7,11-trimethyldodeca-2,4-dienoate

HRID 436301Notes

Reaction equation

HRID 436301 reaction equation
[CH3:1][C:2]([CH:7]=[CH:8][CH2:9][CH:10]([CH3:17])[CH2:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15])=[CH:3][C:4]([OH:6])=[O:5].[CH:18]1([CH2:21]O)[CH2:20][CH2:19]1>C1C=CC=CC=1>[CH3:1][C:2]([CH:7]=[CH:8][CH2:9][CH:10]([CH3:17])[CH2:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15])=[CH:3][C:4]([O:6][CH2:21][CH:18]1[CH2:20][CH2:19]1)=[O:5]

Participants

4

Reactant 2

HCID 75644CyclopropanemethanolHCID 1037233,7,11-Trimethyldodeca-2,4-dienoic acid

Product 1

HCID 54311409Cyclopropylmethyl 3,7,11-trimethyldodeca-2,4-dienoate

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

The acid chloride of 3,7,11-trimethyldodeca-2,4-dienoic acid (0.1 mole) is reacted with 0.2 mole of cyclopropylmethyl alcohol in benzene to yield cyclopropylmethyl 3,7,11-trimethyldodeca-2,4-dienoate.

Sources & evidence

ORD record
ord-135b83ae3815449c84285fda12460642
Source dataset
uspto-grants-1977_02
Patent number
US04008258

Reaction notes

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