Bromine → HCID 23344750, compound

HRID 436355Notes

Reaction equation

BrBr.[C:3]([NH:7][NH:8][C:9]1([C:18]#[N:19])[CH2:14][CH:13]([CH3:15])[CH2:12][C:11]([CH3:17])([CH3:16])[CH2:10]1)([CH3:6])([CH3:5])[CH3:4]>>[C:3]([N:7]=[N:8][C:9]1([C:18]#[N:19])[CH2:14][CH:13]([CH3:15])[CH2:12][C:11]([CH3:17])([CH3:16])[CH2:10]1)([CH3:5])([CH3:4])[CH3:6]

Participants

Reactant 2

HCID 24408Bromine

HCID 23344771HCID 23344771, compound

Product 1

HCID 23344750HCID 23344750, compound

Procedure

1-tert.-butylazo-1-cyano-3,3,5-trimethylcyclohexane was prepared by bromine oxidation of the above 1-tert.-butylhydrazo-1-cyano-3,3,5-trimethylcyclohexane in the same way that 4-tert.-butylhydrazo-4-cyano2,6-dimethylheptane was oxidized in Example VII C. The yield of liquid product was 8.2 g. (63%) and the infrared spectrum was consistent with the structure of the proposed compound.

Sources & evidence

ORD record: ord-99985f566ce04caab5f11d9db0c4bf12
Source dataset: uspto-grants-1977_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04008273

Reaction notes

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