Carbon Tetrachloride → HCID 21452271, compound

HRID 436391Notes

Reaction equation

HRID 436391 reaction equation
[Cl:1]Cl.[CH:3]([CH:5]1[O:9][CH:8]([CH2:10][CH2:11][CH2:12][CH2:13][OH:14])[CH2:7][O:6]1)=C.[C:15]([Cl:19])(Cl)(Cl)Cl>>[Cl:1][CH:3]([CH:5]1[O:9][CH:8]([CH2:10][CH2:11][CH2:12][CH2:13][OH:14])[CH2:7][O:6]1)[CH2:15][Cl:19]

Participants

4

Reactant 3

HCID 5943Carbon TetrachlorideHCID 24526Chlorine2×HCID 212169861,3-Dioxolane-4-butanol, 2-ethenyl-

Product 1

HCID 21452271HCID 21452271, compound

Procedure

Liquid chlorine (228 ml.; 5 moles) was added to a solution of Comonomer B (860 grams; 5 moles), that is, 2-vinyl-4-(4-hydroxybutyl)-1,3-dioxolane, in 3600 ml. of carbon tetrachloride over a period of 4.5 hours while maintaining the temperature at 20°-30° C. by means of intermittent cooling with an ice-bath. When the addition of chlorine was complete, the mixture was stirred at ambient temperature overnight. After removal of solvent by heating the mixture at 51° C. and 1 mm. mercury pressure for one hour, the product was obtained as a colorless viscous material.

Workup

  1. temperatureof intermittent cooling with an ice-bath
  2. customAfter removal of solvent
  3. temperatureby heating the mixture at 51° C.
  4. waitmercury pressure for one hour
  5. customthe product was obtained as a colorless viscous material

Sources & evidence

ORD record
ord-ba5c78241ac24c0fa9a76b037e8339d9
Source dataset
uspto-grants-1977_02
Patent number
US04009129

Reaction notes

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