Aniline → HCID 21431328, compound

Participants

Reaction Steps

To 8.4 grams (.0363 moles) of 1-t-butylazo-1-isothiocyanatocyclohexane stirred with a magnetic stirrer in a 50 ml erlenmeyer flask was added 3.39 grams (.0363 moles) of aniline. The reaction mixture was diluted with pentane and stirred for 6 days. The pentane was stripped from the reaction mixture to leave a white solid weighing 11.5 grams (97% crude yield). The product melted at 110°-113° C. and its infrared spectrum had strong bands at 1515 and 1550 cm-1 and moderate NH bands at 3150 and 3280 cm-1 and the isothiocyanate band at 2040 cm-1 was absent.

Provenance & Evidence