HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Acetic Anhydride → 3-Cyclohexen-1-ol, 3,5,5-trimethyl-, acetate
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Acetic Anhydride | HCID 7918 | — |
| Edukt | Beta-Isophorone | HCID 10108 | — |
| Edukt | Sodium Acetate | HCID 517045 | — |
| Edukt | Sodium borohydride | HCID 4311764 | — |
| Edukt | 3,5,5-Trimethylcyclohex-3-en-1-ol | HCID 11275049 | — |
| Lösungsmittel | Methanol | HCID 887 | — |
| Produkt | 3-Cyclohexen-1-ol, 3,5,5-trimethyl-, acetate | HCID 90791 | — |
Reaktionsschritte
Prepared by reduction by means of sodium borohydride in methanol of β-isophorone [obtained according to J. Am. Chem. Soc., 63, 2308 (1941)] and subsequent acetylation of the obtained 3,5,5-trimethyl-cyclohex-3-en-1-ol by means of acetic anhydride in the presence of sodium acetate at 50° C. during 20 hours.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04029108 |
| Quelldatensatz | uspto-grants-1977_06 |
| ORD ID | ord-f7e2abb6699d49ea804fb4d000f108d2 |
| Quellennotiz | uspto-grants-1977_06 |