HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Chloro-2-methyl-1-propene → 3-[(1,1,1,2,3,3,3-Heptafluoropropan-2-yl)oxy]-2-methylprop-1-ene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Chloro-2-methyl-1-propene | HCID 11241 | — |
| Reactant | Hexafluoroacetone | HCID 12695 | — |
| Reactant | Potassium Fluoride | HCID 522689 | — |
| Reactant | Allyl perfluoroisopropyl ether | HCID 2735866 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 3-[(1,1,1,2,3,3,3-Heptafluoropropan-2-yl)oxy]-2-methylprop-1-ene | HCID 21707322 | 85% |
Reaction Steps
this compound was prepared in a manner analogous to that used for the allyl ether (Example 1), using hexafluoroacetone, anhydrous KF, dimethylformamide, and methallyl chloride. Heptafluoroisopropyl methallyl ether was obtained in 85% yield, b.p. 82° C./760 mm., nD25 1.3129.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04029867 |
| Source dataset | uspto-grants-1977_06 |
| ORD ID | ord-270b279ecbb04b21a91c23346ce44fe6 |
| Source note | uspto-grants-1977_06 |