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HRID437381

反应详情

EQUATION

反应方程式

HRID 437381 的结构方程式

REACTANTS

反应物

1
结构：COCCOCCOCC(=O)Nc1cc(C(=O)O)cc([N+](=O)[O-])c1
HCID70623675

未命名化合物

PRODUCTS

生成物

1
结构：COCCOCCOCC(=O)Nc1cc(N)cc(C(=O)O)c1
HCID70623200

3-Amino-5-[[2-[2-(2-methoxyethoxy)ethoxy]acetyl]amino]benzoic acid

C14H20N2O6

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Pd]
催化剂HCID23938

Palladium

Pd

结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

3-Amino-5-(3,6,9-trioxadecanamido)benzoic Acid [H; T is CH3OCH2CH2OCH2CH2OCH2, Z is OH] was prepared by hydrogenation of 80 g. of 3-nitro-5-(3,6,9-trioxadecanamido)benzoic acid in absolute ethanol in the presence of palladium-on-charcoal catalyst. There was thus obtained 54.7 g. of 3-amino-5-(3,6,9-trioxadecanamido)benzoic acid, m.p. 130.5°-131° C. when recrystallized from isopropyl alcohol.

WORKUP

后处理

  1. customof 3-amino-5-(3,6,9-trioxadecanamido)benzoic acid, m.p. 130.5°-131° C. when recrystallized from isopropyl alcohol