3-iodo-7-fluoro-5H-dibenzo[a,d]cyclohepten-5-one → 3-iodo-5H-dibenzo[a,d]cyclohepten-5-one

HRID 437542Notes

Reaction equation

HRID 437542 reaction equation
[I:1][C:2]1[CH:3]=[CH:4][C:5]2[CH:11]=[CH:10][C:9]3[CH:12]=[CH:13][C:14](F)=[CH:15][C:8]=3[C:7](=[O:17])[C:6]=2[CH:18]=1.IC1C=CC2C=CC3C=CC(C)=CC=3C(=O)C=2C=1>>[I:1][C:2]1[CH:3]=[CH:4][C:5]2[CH:11]=[CH:10][C:9]3[CH:12]=[CH:13][CH:14]=[CH:15][C:8]=3[C:7](=[O:17])[C:6]=2[CH:18]=1

Participants

3

Reactant 2

HCID 214287393-iodo-7-fluoro-5H-dibenzo[a,d]cyclohepten-5-oneHCID 214287553-iodo-7-methyl-5H-dibenzo[a,d]cyclohepten-5-one

Product 1

HCID 202322053-iodo-5H-dibenzo[a,d]cyclohepten-5-one

Procedure

Following the procedure of Step B but substituting for the 3-amino-5H-dibenzo[ a,d]cyclohepten-5-one used therein an equimolecular amount of 3-amino-7-fluoro-5H-dibenzo[a,d]cyclohepten-5-one and 3-amino-7-methyl-5H-dibenzo[a,d]cyclohepten-5-one, there are produced respectively, 3-iodo-7-fluoro-5H-dibenzo[a,d]cyclohepten-5-one and 3-iodo-7-methyl-5H-dibenzo[a,d]cyclohepten-5-one.

Sources & evidence

ORD record
ord-5e4ecf219407457a97ce7223e676ccbe
Source dataset
uspto-grants-1977_06
Patent number
US04031223

Reaction notes

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