HuagongsheHuagongshe Chemistry Print Report · For research reference only
Divinyl sulfone → 1-tert-Butyl-4-{[2-(ethenesulfonyl)ethenyl]sulfanyl}benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Divinyl sulfone | HCID 6496 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | p-t-Butylbenzenesulfenyl chloride | HCID 12801136 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 1-tert-Butyl-4-{[2-(ethenesulfonyl)ethenyl]sulfanyl}benzene | HCID 54545119 | — |
Reaction Steps
In a manner analogous to Example 1, 4-t-butylphenylsulfenyl chloride was added in 1:1 proportion to divinyl sulfone, subjected to treatment with triethylamine in benzene, and purified by column chromatography. The product, vinyl 2-(4-t-butylphenylthio)vinyl sulfone, was obtained as a brown oil which crystallized on standing, m.p. 62°-64° C; calculated for C14H18O2S2 :S, 22.7; found: S, 22.0; Cl, 0.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04031247 |
| Source dataset | uspto-grants-1977_06 |
| ORD ID | ord-0677209030c1412b9ad66da86dbb6f62 |
| Source note | uspto-grants-1977_06 |