HCID 21429309, compound → HCID 21429312, compound

HRID 437682Notes

Reaction equation

HRID 437682 reaction equation
C(O[C:9]1[CH:10]=[C:11]([CH:26]=[CH:27][C:28]=1[O:29]CC1C=CC=CC=1)[O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH:17]([C:22](=O)[CH2:23][CH3:24])C(=O)CC)C1C=CC=CC=1.[OH:37][C:38]1C=C(C=[CH:56][C:57]=1O)OCCCCC(C(=O)CC)C(=O)CC>>[OH:29][C:28]1[CH:9]=[CH:10][C:11]([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:22][CH2:23][CH:24]([C:11](=[O:12])[CH2:10][CH3:9])[C:38](=[O:37])[CH2:57][CH3:56])=[CH:26][CH:27]=1

Participants

3

Reactant 2

HCID 21429309HCID 21429309, compoundHCID 21429328HCID 21429328, compound

Product 1

HCID 21429312HCID 21429312, compound

Procedure

By a similar hydrogenolysis procedure 4-[4-(3,4-dibenzyloxyphenoxy)butyl]-3,5-heptanedione can be coverted to 4-[4-(3,4-dihydroxyphenoxy)butyl]-3,5-heptanedione [I; Ar is 3,4-(HO)2C6H3, Alk is CH2CH2CH2CH2, R and R' are CH3CH2CO].

Sources & evidence

ORD record
ord-25698a3442c24840b1b8f95e8202f2eb
Source dataset
uspto-grants-1977_06
Patent number
US04031246

Reaction notes

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