HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → 2-(Acetyloxy)-5-ethyl-4-methylbenzoic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Acetic Anhydride | HCID 7918 | — |
| Reactant | 5-Ethyl-2-hydroxy-4-methylbenzoic acid | HCID 12366420 | — |
| Solvent | Water | HCID 962 | — |
| Product | 2-(Acetyloxy)-5-ethyl-4-methylbenzoic acid | HCID 12366423 | — |
Reaction Steps
A mixture of 5-ethyl-4-methylsalicylic acid (15.00 g), acetic anhydride (80 ml) and acetic acid (80 ml) was heated under reflux for 1.5 hours, poured into water (1 l) and allowed to stand overnight. The solid formed was filtered off and recrystallised from benzene to give 2-acetoxy-5-ethyl-4-methylbenzoic acid, m.p. 132°-134° C. (Found; C, 64.71; H, 6.46; C12H14O4 requires; C, 64.85; H, 6.35).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04032544 |
| Source dataset | uspto-grants-1977_06 |
| ORD ID | ord-c1a9255f0251434b9273c92b88f565b6 |
| Source note | uspto-grants-1977_06 |