HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-(1-Methoxyethenyl)hept-5-yn-2-one → HCID 86733881, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-(1-Methoxyethenyl)hept-5-yn-2-one | HCID 20372137 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Quinoline | HCID 7047 | — |
| Catalyst | Lindlars catalyst | HCID 131709914 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | HCID 86733881 | HCID 86733881 | — |
Reaction Steps
A mixture of 9.96 g. (60 mmol.) of 2-methoxy-3-acetyl-1-hepten-5-yne, 0.50 g. of Lindlar catalyst, and 10 drops of synthetic quinoline in 100 ml. of ethyl acetate was stirred under one atmosphere of hydrogen until hydrogen absorption was complete, then filtered, concentrated and distilled to afford (Z)-2-methoxy-3-acetyl-1,5-heptadiene; b.p. 64°-66°, (2.0 mmHg).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04032577 |
| Source dataset | uspto-grants-1977_06 |
| ORD ID | ord-a881a08832244aa28f5853a9640aa0a0 |
| Source note | uspto-grants-1977_06 |